| 吖啶-咪唑配体镉(Ⅱ)配合物的合成、表征及阴离子效应 |
| |
| 引用本文： | 王军杰,刘春森,常泽,闫莉芬,卜显和.吖啶-咪唑配体镉(Ⅱ)配合物的合成、表征及阴离子效应[J].无机化学学报,2006,22(8):1443-1448. |
| |
| 作者姓名： | 王军杰 刘春森 常泽 闫莉芬 卜显和 |
| |
| 作者单位： | 南开大学化学系,天津,300071 |
| |
| 基金项目： | 国家高技术研究发展计划(863计划) |
| |
| 摘 要： | 本文报道一个吖啶-咪唑双功能配体L9-(1-咪唑基)吖啶]的2个镉(Ⅱ)配合物Cd(L)2(NO3)2] (1)和Cd(L)2(Ac)(NO3)(H2O)](H2O)3 (2)的合成及结构表征，并探讨了阴离子对配合物结构的影响，结果表明：不同的阴离子对配合物的结构具有重要影响。
|
| 关 键 词： | 吖啶-咪唑配体 晶体结构 π-π堆积 阴离子效应 |
| 文章编号： | 1001-4861（2006）08-1443-06 |
| 收稿时间： | 2006-06-15 |
| 修稿时间： | 2006-07-11 |
Synthesis, Crystal Structure and Anion Effect of Cd(Ⅱ) Complexes with Acridine-imidazole Ditopic Ligand |
| |
| WANG Jun-Jie,LIU Chun-Sen,CHANG Ze,YAN Li-Fen and BU Xian-He.Synthesis, Crystal Structure and Anion Effect of Cd(Ⅱ) Complexes with Acridine-imidazole Ditopic Ligand[J].Chinese Journal of Inorganic Chemistry,2006,22(8):1443-1448. |
| |
| Authors: | WANG Jun-Jie LIU Chun-Sen CHANG Ze YAN Li-Fen and BU Xian-He |
| |
| Institution: | Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
| |
| Abstract: | Two new Cd(II) complexes with acridine-imidazole ditopic ligand L (L=9-(1-imidazolyl)acridine), Cd(L)2(NO3)2 (1) and Cd(L)2(Ac)(NO3)(H2O)(H2O)3 (2), were synthesized and structurally characterized by IR and single crystal X-ray structural analysis. 1 has a 1D chain structure bridged by NO3- anions, whereas 2 takes a mononuclear structure. The structural difference of the two complexes is attributable to the difference of counter anions. CCDC: 606068, 1; 606069, 2. |
| |
| Keywords: | |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
