Kinetic regularities of micellar catalysis in the dephosphorylation with peroxide anion |
| |
| Authors: | L. N. Vakhitova K. V. Matvienko A. V. Skrypka N. A. Taran N. G. Razumova A. F. Popov V. A. Savelova |
| |
| Affiliation: | 1.Litvinenko Institute of Physical Organic and Coal Chemistry,National Academy of Sciences of Ukraine,Donetsk,Ukraine |
| |
| Abstract: | The acid-base equilibrium of hydrogen peroxide in water solutions of cetyltrimethylammonium bromideand the reactivity of hydroxide and peroxide anions with respect to 4-nitrophenyl diethyl phosphate were investigated. In the micelles the acid ionization constant of the hydrogen peroxide increased three-fold. The application of the pseudophase distribution model under the conditions of competitive sorption of HO− and HOO− anions with the micelles of cetyltrimethylammonium bromide to the estimation of the main kinetic parameters of the micellar process was tested. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
