| 超分子三维氢键网络：{[Cu(phen)3](SO4)(H3PCA)2(8H2O)}的晶体结构 |
| |
| 引用本文： | 何洪银,朱龙观. 超分子三维氢键网络：{[Cu(phen)3](SO4)(H3PCA)2(8H2O)}的晶体结构[J]. 无机化学学报, 2003, 19(3): 317-320 |
| |
| 作者姓名： | 何洪银 朱龙观 |
| |
| 作者单位： | 浙江大学化学系,杭州,310027 |
| |
| 基金项目： | 国家自然科学基金资助项目(No.50073019)。 |
| |
| 摘 要： | A new complex， {[Cu(phen)3](SO4)(H3PCA)2(8H2O)}， was synthesized and structurally characterized by single-crystal X-ray analysis. The complex is composed of copper cations， sulfate anions， 1，10-phenanthroline， protocatechuic acid and lattice water molecules. The structure of H3PCA， SO42- and waters comprises packing of anionic three-dimensional network by hydrogen bonds with cavities. The complex can be considered as a model of host/guest supramolecule. The three-dimensional hydrogen-bonding network is the host species. The Cu(phen)32+ cations， guest species， occupied the cavities of the host. And the results demonstrate that the form of protocatechuic acid at pH< 1 should be free ligand. CCDC： 191733.
|
| 关 键 词： | 铜 二维网络 三维网络 超分子 氢键 |
| 修稿时间： | 2002-09-20 |
3D Supramolecular Hydrogen Bonding Network:Crystal Structure of {[Cu(phen)3] (SO4)(H3PCA)2(8H2O)} |
| |
| HE Hong-Yin and ZHU Long-Guan. 3D Supramolecular Hydrogen Bonding Network:Crystal Structure of {[Cu(phen)3] (SO4)(H3PCA)2(8H2O)}[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(3): 317-320 |
| |
| Authors: | HE Hong-Yin and ZHU Long-Guan |
| |
| Abstract: | |
| |
| Keywords: | copper 2-D network 3-D network supramolecule hydrogen bonding |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
