| 具有拟除虫菊酯活性的肟醚类化合物 |
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| 引用本文： | 黄润秋,柴有新,毕富春,陈学仁,王银淑. 具有拟除虫菊酯活性的肟醚类化合物[J]. 高等学校化学学报, 1983, 4(5): 589 |
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| 作者姓名： | 黄润秋 柴有新 毕富春 陈学仁 王银淑 |
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| 作者单位： | 南开大学元素有机化学研究所 |
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| 摘 要： | 本文报导一类具有拟除虫菊酯活性的肟醚类化合物的合成、结构特性及生物活性。其中某些化合物对粘虫等有很高杀虫活性而对温血动物急性毒性很低,有希望发展成一类新型杀虫剂。
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| 收稿时间： | 1982-03-08 |
THE OXIME-ETHER COMPOUNDS OF PYRETHROID-LIKE |
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| Huang Runqiu,Chai Youxin,Bi Fuchun,Chen Xueren,Wang Yinshu. THE OXIME-ETHER COMPOUNDS OF PYRETHROID-LIKE[J]. Chemical Research In Chinese Universities, 1983, 4(5): 589 |
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| Authors: | Huang Runqiu Chai Youxin Bi Fuchun Chen Xueren Wang Yinshu |
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| Affiliation: | Institute of Elemento-Organic Chemistry, Nankai University, Tianjin |
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| Abstract: | The present report deals with the synthesis of a series of pyrethroid-like oxime-ether compounds, their structure characteristic and the relation of structure-biologic activity.Compounds I ( R = h alogen, and R'= #em/em#-propyl or cyclo-propyl ) show high insecticidal activities against Army worms ( Leucania Separata). Their toxicities ( LD50) close to that of Shumizize(S-5602)and surpass that of DDT.The acute oral toxi-city of compound I ( R = Cl, R'=#em/em#-pr) against mice indicated both E-and Z-isomers have LD50>4500mg/Kg. Similar to conventional pyrethro-ids, both isomers did not inhibit choline esterase. |
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