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Density, viscosity, and excess properties of the binary mixture of diethylene glycol monomethyl ether + water at T = (293.15, 303.15, 313.15, 323.15, 333.15) K under atmospheric pressure
Authors:Xin-Xue Li  Wei-Dong Zhou  Xiao-Ya Li  Jian-Ling Sun  Wei Jiang
Institution:aDepartment of Chemistry, University of Science and Technology Beijing, Beijing, China
Abstract:Densities and viscosities have been measured as a function of composition for the binary liquid mixture of diethylene glycol monomethyl ether CH3O(CH2)2O(CH2)2OH + water at T = (293.15, 303.15, 313.15, 323.15, 333.15) K under atmospheric pressure. Densities were determined using a capillary pycnometer. Viscosities were measured with Ubbelohde capillary viscometer. From the experimental data, the excess molar volumes VE, and viscosity deviations δη, and the excess energies of activation for viscous flow ΔG*E were calculated. These data have been correlated by the Redlich–Kister type equations to obtain their coefficients and standard deviations. The results suggest that molecular interaction between diethylene glycol monomethyl ether and water is strong.
Keywords:Density  Viscosity  Diethylene glycol monomethyl ether  Excess property
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