Single-sided sensor for high-resolution NMR spectroscopy |
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Authors: | Perlo J Casanova F Blümich B |
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Institution: | Institut für Technische Chemie und Makromolekulare Chemie, RWTH Aachen, D-52056, Germany. |
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Abstract: | The unavoidable spatial inhomogeneity of the static magnetic field generated by open sensors has precluded their use for high-resolution NMR spectroscopy. In fact, this application was deemed impossible because these field variations are usually orders of magnitude larger than those created by the microscopic structure of the molecules to be detected. Recently, chemical shift resolved NMR spectra were observed for the first time outside a portable single-sided magnet by implementing a method that exploits inhomogeneities in the rf field designed to reproduce variations of the static magnetic field. In this communication, we describe in detail the magnet system built from permanent magnets as well as the rf coil geometry used to compensate the static field variations. |
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Keywords: | Single-sided NMR Chemical shift Mobile probes Inhomogeneous magnetic fields |
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