| Synthesis and Crystal Structure of (1R,2S,3S,4S)-(6-O-Acetyl-1,2-O-isoproplidene-3,5-dideoxy-α-D-glucofuranoso)-1,3,5-trihydro-2,3-oxathiaindene-2,2-dioxide |
| |
| 作者姓名： | 张磊 魏国华 杜宇国 |
| |
| 作者单位： | State;Laboratory;Environmental;Chemistry;Ecotoxicology;Research;Center;Eco-environmental;Sciences;Chinese;Academy; |
| |
| 基金项目： | supported by the National Natural Science Foundation of China (NSFC#30701043) |
| |
| 摘 要： | (1R,2S,3S,4S)-(6-O-Acetyl-1,2-O-isoproplidene-3,5-dideoxy-α-D-glucofuranoso)-1,3,5-trihydro-2,3-oxathiaindene-2,2-dioxide(C11H16O8S,Mr=308.30) was synthesized and structurally characterized by NMR,MS and single-crystal X-ray diffraction.It belongs to the triclinic system,space group P1 with a=7.0836(14),b=10.832(2),c=14.895(3),α=96.01(3),β=98.85(3),γ=108.59(3)o,V=1055.8(4)3,Z=3,Dc=1.455g/cm3,F(000)=486,μ=0.264mm-1,the final R=0.0360 and wR=0.0712.It is a tricyclic sultone derivative composed of three five-membered rings.
|
| 关 键 词： | 3S技术 乙酰基 二氧化硫 合成 4型 O型 三维 脱氧 |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
