The first (31P, 17O,and 103Rh) NMR observation complex formation of rhodium(III) with phosphoric acid |
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| Authors: | M. A. Fedotov A. V. Belyaev |
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| Affiliation: | (1) Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090, Russia;(2) Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia |
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| Abstract: | 31P, 17O, and 103Rh NMR spectroscopy shows that rhodium(III) reacts with phosphoric acid to generate polynuclear aquaphosphate complexes in which phosphate ions mostly have a bridging function. Assignment of 103Rh NMR signals in dominant rhodium complexes is suggested. |
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