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Asymmetric synthesis of the C(1)---C(47) backbone of antitumour antibiotic A83586C |
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| Authors: | Karl J Hale Jiaqiang Cai Vern M Delisser |
| Institution: | The Christopher Ingold Laboratories, Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, UK |
| Abstract: | Protected pentapeptide 9 has been converted to hexapeptide 3 and this chemoselectively coupled to activated ester 2 to give 1 after glycal hydration during SiO2 flash chromatography. |
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