Synthesis,Crystal Structure of Ruthenium 1,2-Naphthoquinone-1-oxime Complex and Its Mediated C—C Coupling Reactions of Terminal Alkynes |
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作者姓名: | 孙克 黄永德 刘晓霞 张宝砚 |
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作者单位: | Department of Chemistry,Department of Chemistry,Department of Chemistry,Department of Chemistry Northeastern University,Shenyang,Liaoning 110004,China,The University of Hong Kong,Hong Kong,China,Northeastern University,Shenyang,Liaoning 110004,China,Northeastern University,Shenyang,Liaoning 110004,China |
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基金项目: | ProjectsupportedbytheUniversityofHongKong ,HongKongResearchGrantsCouncilandEducationalMinistryofChina |
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摘 要: | IntroductionRecently ,wehavereportedthecoordinationchem istryof 1,2 naphthoquinone mono oxime (nqoH)towardsplatinumgroupmetalsincludingrutheniumandrhodi um .1 8ThereactionsofnqoHwithrutheniumcarbonyl[Ru3(CO) 12 ]leadtofiveisomersofmononuclearrutheni umcarbonylcomplexesof 1,2 naphthoquinone mono oxime .1 3Thepresenceoftheliablecarbonylligandsofferstheopportunitytointroduceavarietyofligandswithspe cificfunctionalgroupsintothemolecule .3Bythisstrategy ,metal containingpolymers ,supramolecular…
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