Synthesis and structures of N,N,O-scorpionatoruthenium(II) complexes featuring “non-innocent” o-benzoquinonediimines |
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| Authors: | Jae-Hwan Oh Takanori Nishioka Ryoji Masui Eiji Asato Isamu Kinoshita Satoshi Takara |
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| Institution: | 1. Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan;2. Department of Material Science, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan |
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| Abstract: | A series of ruthenium(II) complexes bearing redox-active o-benzoquinonediimines (o-bqdi) was synthesized and characterized. Reactions of RuCl(bdmpza)(η4-cod)] (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetato; cod = 1,5-cyclooctadiene) and 1,2-benzenediamines such as o-phenylenediamine (o-pdaH2), 4,5-difluoro-1,2-benzenediamine (o-pdaF2), 4,5-dichloro-1,2-benzenediamine (o-pdaCl2), and 4,5-dimethoxy-1,2-benzenediamine (o-pda(OMe)2) afforded RuCl(bdmpza)(o-bqdiX2)] (X = H, 1; X = F, 2; X = Cl, 3; X = OMe, 4). |
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