Microbalance Techniques in Design and Control of Synthetic Carbons |
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Authors: | Puziy A M Poddubnaya O I |
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Institution: | (1) Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Naumov St. 13, 252164 Kyiv, Ukraine |
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Abstract: | Peculiarities of carbonization of two styrene/divinylbenzene precursors (one sulfonated, another aminated and phosphorylated)
have been investigated by thermogravimetry and differential thermal analysis. It was shown that phosphorus compounds incorporate
into carbon structure and cause delayed carbonization. Porous structure and surface properties of synthetic carbons have been
investigated by standard (BET, αs method, DA) and advanced (AED, PSD, regularization) methods from benzene and water adsorption isotherms. It was shown that
phosphorus-containing carbon is less microporous and shows highly hydrophilic surface.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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Keywords: | adsorption adsorption energy distribution carbonization of polymers pore size distribution porosity thermogravimetric analysis |
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