| Crystal Structure of a Ternary Copper(Ⅱ) Complex of N,N'-(p-Xylylene)dialanine Acid and 1,10-Phenanthroline |
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| 作者姓名： | JIA Lei XO Jun HAO Zhong-Yan CHEN Long-Hai CHENG Fei-Xiang TANG Ning |
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| 作者单位： | JIA Lei(Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, China);XU Jun,HAO Zhong-Yan,CHEN Long-Hai,CHENG Fei-Xiang,TANG Ning(Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China) |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China （20571035） and the Ministry of Education, Singapore through NUS （FRC （}rant No. R143-000-371-112） |
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| 摘 要： | The compound [Cu2(bpy)2(PDIAla)(H2O)2](ClO4)2·H2O(H2PDIAla = N,N'-(p-xylylene)dialanine,bipy = 2,2'-bipyridine) 1 has been synthesized and structurally determined by single-crystal X-ray diffraction,elemental analyses and IR spectroscopy.The crystal belongs to the monoclinic system,space group P21 with a = 10.9772(6),b = 18.5464(9),c = 11.0790(6) ,β = 116.3110o,V = 2021.87(18) 3,Z = 2,Dc = 1.594 Mg/m3,Mr = 970.70,μ = 1.260 mm-1,F(000) = 996,λ(MoKα) = 0.71073 ,the final R = 0.0400 and wR = 0.1050 for all observed reflections.In the structure,the O(5)-H(52)···O(4) hydrogen bonding between aqua ligand and carbonyl oxygen of the H2PDIAla ligand along the c axis produce hydrogen-bonded helices which are assembled along the b axis through O(61)-H(61)···O(2) and N(6)-H(6N)···O(2) interactions to form 2-D layers that are further linked by π···π interactions between bpy ligands to yield a three-dimensional supramolecular network.
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| 关 键 词： | 晶体结构 对二甲苯 邻菲罗啉 配合物 三元 射线衍射分析 红外光谱测定 铜 |
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