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The asymmetric synthesis of cis-substituted cyclopropanecarboxylic acid derivatives |
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| Authors: | Philip W Ambler Stephen G Davies |
| Institution: | The Dyson Perrins Laboratory, South Parks Road, Oxford, OX1 3QY, U.K. |
| Abstract: | The asymmetric synthesis of cis-substituted cyclopropanecarboxylic acid derivatives is achieved via stereoselective electrophilic methylene transfer to Z- ,β-unsaturated acyl ligands bound to the iron chiral auxiliary (η5-C5H5Fe(CO)(PPh3)]. |
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