A 3D Metal‐organic Framework Containing [Cd(3‐CPOA)]n (3‐CPOA2– = 3‐Carboxyphenoxyacetato Dianion) Expanded by 4,4′‐Bipyridine |
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| Authors: | Zhao‐Peng Deng Li‐Hua Huo Shan Gao Prof Dr Hui Zhao |
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| Institution: | Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Habin, P. R. China |
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| Abstract: | The hydrothermal reaction of Cd(NO3) · 4H2O with 4,4′‐bipyridine (bipy) and 3‐carboxyphenoxyacetatic acid (3‐H2CPOA) afforded a 3D metal‐organic framework (MOF) Cd(3‐CPOA)(bipy)]n · 3.5nH2O, which was characterized by elemental analyses, IR spectroscopy, thermogravimetric analyses, and X‐ray diffraction. The single‐crystal structural analysis revealed that it has a Cds‐type topological network with 1D channels that contain encapsulated water molecular tapes. |
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| Keywords: | Coordination polymers Hydrothermal synthesis Cadmium 3‐Carboxyphenoxyacetatic acid Topology |
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