Nanoparticles consisting of optically active helical polymers: Preparation via aqueous catalytic miniemulsion polymerization and the effects of particles size on their optical activity |
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| Authors: | Xiaofeng Luo Naiwen Kang Lei Li Jianping Deng Wantai Yang |
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| Institution: | 1. State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China;2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China |
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| Abstract: | This article reports a class of nanoscale materials, that is, optically active nanoparticles consisting of helical‐substituted polyacetylenes. Such nanoparticles were prepared via aqueous catalytic miniemulsion polymerization, by which nanoparticles with a wide range of size (diameter: 60–400 nm) can be easily prepared. The nanoparticles could be obtained in quantitative monomer conversions. Large specific rotations and intense circular dichroism effects demonstrated that the nanoparticles possessed large optical activities; moreover, the optical activities were found to increase with a decrease in particle size. From the obtained polymer nanoparticles and with poly(vinyl alcohol) (PVA) as supporting material, composite films were further prepared and also exhibited considerable optical activities. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1661–1668, 2010 |
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| Keywords: | emulsion polymerization helical structure miniemulsion polymerization nanoparticles optically active polyacetylenes substituted polyacetylene |
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