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Enantioselective organocatalytic conjugate addition of organoboron nucleophiles
Authors:Truong N. Nguyen  Jeremy A. May
Affiliation:Department of Chemistry, University of Houston, 112 Fleming Building, Houston, TX 77204-5003, United States
Abstract:This review covers the use of organoboron nucleophiles in enantioselective conjugate additions catalyzed by organic-based catalysts. It is divided into sections based on the type of nucleophile, with each section arranged in roughly chronological order. The categories of nucleophiles are alkynyl, alkenyl, and aryl boronates or borates. The principle modes of catalysis, iminium formation and boron chelation, are covered.
Keywords:Conjugate addition  Organocatalysis  Organoboronates  Enantioselective catalysis
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