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The improvement of electro‐optical properties of polymer‐dispersed liquid crystals using copolymer macroinitiator with different glass transition temperature
Authors:Xin Du  Bin Yan  Jiali Yao  Shu Chen  Minke Li  Yinghan Wang
Institution:State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, People's Republic of China
Abstract:In this article, copolymer macroinitiators prepared with styrene and iso‐octyl acrylate by reversible additional‐fragmental chain transfer polymerization were used to prepare polymer‐dispersed liquid crystals (PDLCs) with methyl acrylate. The electro‐optical properties of the PDLCs were investigated. The results showed that the glass transition temperature (Tg) of the macroinitiator has a great influence on the memory effect of the resulting PDLCs. Low driving voltage and low memory effect PDLCs could easily be obtained with copolymer macroinitiators. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010
Keywords:copolymer  glass transition temperature  living radical polymerization  optics  PDLC  RAFT
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