Thermodynamic characterization of poly(2,2,3,3,3‐pentafluoropropyl methacrylate) |
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| Authors: | Stella K Papadopoulou Ioannis Karapanagiotis Ioannis Zuburtikudis Costas Panayiotou |
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| Institution: | 1. Department of Chemical Engineering, Laboratory of Physical Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece;2. Ormylia Foundation, Art Diagnosis Center, Ormylia, Chalkidiki 63071, Greece;3. Department of Industrial Design Engineering, TEI of Western Macedonia, Kozani 50100, Greece |
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| Abstract: | The thermodynamic characterization of a fluorinated methacrylic homopolymer was conducted by means of inverse gas chromatography (IGC), at infinite dilution. The homopolymer under study, poly(2,2,3,3,3‐pentafluoropropyl methacrylate) (PPFPMA), was synthesized via a free radical polymerization reaction and was characterized by the employment of Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and size exclusion chromatography (SEC) techniques. The specific retention volume of 15 solvents, used as probes, was used for the assessment of the Flory–Huggins interaction parameter, the weight fraction activity coefficient, the molar heat, energy and entropy of sorption, the partial heat of mixing of the probes, as well as the solubility parameter of the polymer. The results demonstrate that PPFPMA is insoluble in most organic solvents even at increased temperatures, with the exception of solvents like 2‐Butanone. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1826–1833, 2010 |
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| Keywords: | inverse gas chromatography thermodynamics fluoropolymers synthesis |
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