Hydrogen bonding networks controllable by the substitution position of tetrathiafulvalene on the pyridine ring |
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Authors: | Jing Xu Yibao Li Lejia Wang Xiaoyang Zhu Xunwen Xiao Yanfang Geng Qingdao Zeng |
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Institution: | CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology (NCNST), Beijing 100190, China; Key Laboratory of Organo-pharmaceutical, Chemistry Institution, Gannan Normal University, Ganzhou 341000, China; College of Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China |
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Abstract: | Tetrathiafulvalene (TTF), as a classical building unit, has attracted considerable attention, especially its functional derivatives. Hydrogen bonding (H-bonding) networks are a class of traditional and stable nanostructures, which play an important role in two-dimensional self-assembly and multi-component co-assembly. In this paper, we studied the regulation of H![/>bonding networks by functional groups in TTF derivatives. The results indicate that the position of pyridine on TTF not only affects their self-assembly structures in different solvents, but also controls the H<img style=](https://sdfestaticassets-eu-west-1.sciencedirectassets.com/shared-assets/16/entities/sbnd) | |
Keywords: | Tetrathiafulvalene Pyridine Solvent Network Self-assembly |
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