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Synthesis of cyclophellitol utilizing a palladium chloride mediated-Ferrier-II rearrangement |
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| Authors: | Takahashi Hideyo Ikegami Shiro |
| Affiliation: | Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-0195, Japan. |
| Abstract: | Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl2. |
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