Ringschlüsse an Chinonylmethanfarbstoffen und analogen Merocyaninen. 3. Mitteilung. Chinoide Derivate des anellierten Tetrahydro-isochinolino-chinoxalins. Ringschluss nach 1,7-Verschiebung von Wasserstoff? |
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Authors: | Dieter Schelz Martin Priester |
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Abstract: | Cyclization Reactions of Quinonylmethane Dyes and Analogous Merocyanines. 3. Communication. Quinoid Derivatives of the Anellated Tetrahydro-quinoxalino-quinoxaline. Cyclization Following 1,7-Hydrogene-Shift? The title compounds were obtained by proton catalyzed cyclization of the corresponding 2-(1-alkyl-3-methyl-1,2-dihydroquinoxalin-2-ylidenmethyl)-1,4-naphtho- and 1,4-anthraquinones. The visible and 1H-NMR.- and some mass spectra of the dyes are given. Mechanistic aspects of the new-type cyclization reaction are discussed. |
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