Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III) complexes with 2,3-quinoxalinediolate ligands |
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| Authors: | Vallejo Julia Cano Joan Castro Isabel Julve Miguel Lloret Francesc Fabelo Oscar Cañadillas-Delgado Laura Pardo Emilio |
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| Affiliation: | Departament de Química Inorgànica, Instituto de Ciencia Molecular, Universitat de València, 46980 Paterna, València, Spain. |
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| Abstract: | The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(III) ions in basic media in air affords a new family of carbonato-bridged M(2)(III) compounds (M = Pr, Gd and Dy), the Dy(2)(III) analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets. |
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