两种新型不饱和苯硫酚酯光学树脂单体的合成 |
| |
引用本文: | 陈凯,周正发,徐卫兵. 两种新型不饱和苯硫酚酯光学树脂单体的合成[J]. 合成化学, 2016, 24(7): 628-630. DOI: 10.15952/j.cnki.cjsc.1005-1511.2016.07.15261 |
| |
作者姓名: | 陈凯 周正发 徐卫兵 |
| |
作者单位: | 合肥工业大学 化学与化工学院,安徽 合肥 230009 |
| |
摘 要: | 以4-氯苯硫酚和4-溴苯硫酚为原料,通过正常滴加酰氯的低温相转移催化法(PTC)以及反向滴加碱溶液PTC法,与丙烯酰氯经酯化反应合成了两种新型的不饱和苯硫酚酯光学树脂单体--丙烯酸-4-氯苯硫酚酯和丙烯酸-4-溴苯硫酚酯,总收率分别为55.0%和78.2%,其结构经1H NMR, 13C NMR, IR和元素分析表征。
|
关 键 词: | 苯硫酚 不饱和苯硫酚酯 相转移催化 光学树脂单体 合成 折射率 |
收稿时间: | 2015-07-03 |
Synthesis of Two Novel Unsaturated Thiophenol Ester Optical Resin Monomers |
| |
Abstract: | Two novel unsaturated thiophenol ester optical resin monomers , 4-chlorothiophenol acrylate and 4-bromothiophenol acrylate with total yields of 55 .0% and 78 .2%, were synthesized by normal dropping chloride low-temperature phase transfer catalysis ( PTC) method and reverse dropping alkaline solution PTC method using 4-chlorothiophenol , 4-bromothiophenol and acrylyl chloride as the starting materials.The structures were characterized by 1 H NMR, 13 C NMR, IR and elemental analysis . |
| |
Keywords: | thiophenol unsaturated thiophenol ester phase transfer catalysis optical resin monomer synthesis refractive index |
本文献已被 CNKI 万方数据 等数据库收录! |
| 点击此处可从《合成化学》浏览原始摘要信息 |
|
点击此处可从《合成化学》下载全文 |