| CO_2响应石墨烯体系的制备及其性能研究 |
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| 引用本文： | 何帅,刘兴利,谭炯,李晖,朱刚,王继宇. CO_2响应石墨烯体系的制备及其性能研究[J]. 合成化学, 2016, 0(9). DOI: 10.15952/j.cnki.cjsc.1005-1511.2016.09.16160 |
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| 作者姓名： | 何帅 刘兴利 谭炯 李晖 朱刚 王继宇 |
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| 作者单位： | 1. 西南民族大学化学与环境保护工程学院,四川成都,610041;2. 中国科学院成都有机化学研究所,四川成都,610041 |
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| 基金项目： | 四川省应用基础研究资助项目(2014JY0159)，四川省教育厅科研资助项目(15ZB0485)，西南民族大学中央高校基本科研业务费专项资助项目(2016NZYQN16) |
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| 摘 要： | 利用CO_2响应性的含芘聚合物(PNDV)作为分散剂,通过π-π共轭作用力成功附着在石墨烯表面,从而制得一种稳定的石墨烯分散体系。采用UV-Vis、IR、荧光光谱和透射电子显微镜对体系中石墨烯的分散性和CO_2响应性能进行表征。结果表明:PNDV可修饰在石墨烯表面,形成含芘聚合物和石墨烯的杂化体(PNDV-RGO),得到稳定均匀的石墨烯分散溶液。透射电镜显示石墨烯在体系中以单片层形式分布,最大宽度约1μm。在交替通入CO_2/N2后,PNDV-RGO杂化体表现出明显的分散/聚集现象。
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| 关 键 词： | 石墨烯 π-π共轭作用 分散体系 CO2响应 功能材料 |
Preparation and Properties of CO2-Response Graphene System |
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| Abstract: | The stable graphene dispersion system was prepared using CO 2-response pyrene-contained polymer as a dispersant , which adsorbed on graphene ' s surface viaπ-πconjugate action .The dispers-ibility and CO2-response performance of graphene system were characterized by UV-Vis, IR, fluores-cence and transmission electron microscope .The results showed that pyrene-contained polymer could adsorb on graphene′s surface , so it could form PNDV-RGO complex and the stable graphene dispersion was obtained .The single-layer graphene with 1μm in width could be seen by transmission electron mi-croscope.Furthermore, after bubbling CO2/N2 in turn, graphene in system indicated dispersion/aggre-gation phenomena . |
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| Keywords: | graphene π-πconjugate action dispersion system CO2 response functional material |
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