Mechanism of isotope exchange of dihydrogen with liquid water catalyzed by hydroxide ions |
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Authors: | A A Medvinskii N N Bulgakov Yu M Baikov G G Saveliev and E K Shalkova |
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Institution: | (1) Polytechnical Institute, Tomsk, USSR;(2) Institute of Catalysis, Novosibirsk, USSR;(3) Physico-Technical Institute, Leningrad, USSR |
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Abstract: | In the analysis of the reaction between dissolving hydrogen and aqueous alkali hydroxide solutions the interaction of hydrogen with the molecular ion (H3O2)– should be studied. This interaction is analyzed by the interacting bonds method. The activation energy (Ea) is estimated.
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![kcy](/content/j61916132785w496/xxlarge1082.gif) ![ucy](/content/j61916132785w496/xxlarge1091.gif) ![lcy](/content/j61916132785w496/xxlarge1083.gif) ![yacy](/content/j61916132785w496/xxlarge1103.gif) ![rcy](/content/j61916132785w496/xxlarge1088.gif) ![ncy](/content/j61916132785w496/xxlarge1085.gif) ![ycy](/content/j61916132785w496/xxlarge1099.gif) ![icy](/content/j61916132785w496/xxlarge1080.gif) ![ocy](/content/j61916132785w496/xxlarge1086.gif) ![ncy](/content/j61916132785w496/xxlarge1085.gif) ![ocy](/content/j61916132785w496/xxlarge1086.gif) (H3O2)–. ![Pcy](/content/j61916132785w496/xxlarge1055.gif) ![rcy](/content/j61916132785w496/xxlarge1088.gif) ![ocy](/content/j61916132785w496/xxlarge1086.gif) ![vcy](/content/j61916132785w496/xxlarge1074.gif) ![ocy](/content/j61916132785w496/xxlarge1086.gif) ![dcy](/content/j61916132785w496/xxlarge1076.gif) ![icy](/content/j61916132785w496/xxlarge1080.gif) ![tcy](/content/j61916132785w496/xxlarge1090.gif) 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![acy](/content/j61916132785w496/xxlarge1072.gif) ![tscy](/content/j61916132785w496/xxlarge1094.gif) ![icy](/content/j61916132785w496/xxlarge1080.gif) (Ea).
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