3d-Metal Nitroprusside–Thiosemicarbazide Complexes: Synthesis and Properties |
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| Authors: | Koksharova T V Parovik N N |
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| Institution: | (1) Mechnikov State University, ul. Petra Velikogo 2, Odessa, 270100, Ukraine |
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| Abstract: | The following complexes were synthesized from 3d-metal nitroprussides and thiosemicarbazide: CrL3]Fe(CN)5H2O] · 6H2O, FeL3]2Fe(CN)5NO]3 · 14H2O, CoL3]2Fe(CN)5NO]3 · 4H2O, NiL2]Fe(CN)5NO], CuL2]Fe(CN)5NO] · 5H2O, and ZnL2]Fe(CN)5NO], where L is thiosemicarbazide. Their structures and properties were studied by IR and diffuse reflection spectroscopies and DTA. |
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