Mild chlorination of aromatic compounds with tin(IV) chloride and lead tetraacetate |
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| Affiliation: | 1. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS/Université de Rennes 1, Campus de Beaulieu, 35042 Rennes, France;2. TrisKem International, 3 rue des champs Géons, ZAC de l’Eperon, 35170 Bruz, France;3. Institut Jean Lamour, Electrochimie des Matériaux, UMR 7198 CNRS/Université de Lorraine, 1 bd Arago, 57078 Metz, France;1. Department of Physics, University of Pretoria, Hatfield campus, Pretoria 0002, South Africa;2. National Institute for Theoretical Physics, Johannesburg, 2000, South Africa |
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| Abstract: | SnCl4/Pb(OAc)4 acts as a safe source of Cl2 for the chlorination of aromatic compounds. A variety of aromatic compounds are effectively chlorinated with SnCl4/Pb(OAc)4 under mild conditions. The mixture is a selective chlorinating agent, particularly with polyalkylbenzenes, polycyclic aromatic compounds and anisoles. |
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