| 铜二取代三元杂多化合物的制备、晶体结构和性质 |
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| 引用本文： | 王敬平,韩秋霞,牛景扬.铜二取代三元杂多化合物的制备、晶体结构和性质[J].无机化学学报,2002,18(9):933-937. |
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| 作者姓名： | 王敬平 韩秋霞 牛景扬 |
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| 作者单位： | 河南大学化学化工学院,开封,475001 |
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| 基金项目： | 河南省杰出青年基金资助项目(No.)，河南省自然科学基金资助项目(No.004031800和004040300)。 |
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| 摘 要： | The half Dawson structure complex has been prepared by reaction of Na2WO4·2H2O, Na2MoO4·2H2O and NaH2PO4 in water. TBA]4H3PW6Mo4Cu2O38(H2O)2] have been synthesized by reaction of PW5Mo4O34]9- and Cu2+ in water and recrystallized in a mixed acetone/water solvent. They were characterized by elemental analyses, IR spectra and electronic spectra. The crystal structure of TBA]4H3PW6Mo4Cu2O38(H2O)2] has been determined by X-ray structure analysis for the first time, which belongs to trigonal with space group R-3, a=b=c=1.53081 (18) nm, α=β=γ=109.458(17)°, Z=1, Dc=3.141Mg·m-3, R=0.0780, Rw=0.1480. The sites of the molybdenum, tungsten and copper atoms are disordered over 12 possible locations in the crystal, and the anion has a high symmetry due to the disorder of the molybdenum, tungsten and copper atoms. CCDC: 176656.
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| 关 键 词： | 过渡金属 杂多酸 Keggin结构 晶体结构 |
| 修稿时间： | 2002年4月3日 |
Synthesis, Characterization and Crystal Structure of New Transition Metal Disubstituted Ternary Heteropolyoxometallate |
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| WANG Jing-Ping,HAN Qiu-Xia and NIU Jing-Yang.Synthesis, Characterization and Crystal Structure of New Transition Metal Disubstituted Ternary Heteropolyoxometallate[J].Chinese Journal of Inorganic Chemistry,2002,18(9):933-937. |
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| Authors: | WANG Jing-Ping HAN Qiu-Xia and NIU Jing-Yang |
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| Institution: | Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001,Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 and Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 |
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| Abstract: | |
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| Keywords: | transition metal heteropolyoxometallate Keggin structure crystal structure |
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