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Palladium-catalyzed selective carboelimination and cross-coupling reactions of benzocyclobutenols with aryl bromides
Authors:Chtchemelinine Andrei  Rosa David  Orellana Arturo
Affiliation:Department of Chemistry, York University, 440 Chemistry Building, 4700 Keele Street, Toronto, ON, Canada M3J 1P3.
Abstract:The palladium-catalyzed selective β-carboelimination and cross-coupling chemistry of benzocyclobutenols is described. In contrast to the base-mediated ring-opening reactions of benzocyclobutenols, this variant proceeds with exclusive cleavage of the proximal bond.
Keywords:
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