首页 | 本学科首页   官方微博 | 高级检索  
     检索      


The gold(III) tetra­chloride salt of L‐cocaine
Authors:Matthew R Wood  Thomas A Brettell  Roger A Lalancette
Abstract:The title salt, methyl (1R,2R,3S,5S,8S)‐3‐benzoyl­oxy‐8‐methyl‐8‐aza­bicyclo­3.2.1]octane‐2‐carboxyl­ate tetra­chloro­aurate(III), (C17H22NO4)AuCl4], has its protonated N atom intra­molecularly hydrogen bonded to the O atom of the methoxy­carbonyl group N?O = 2.755 (6) Å and N—H?O = 136°]. Two close inter­molecular C—H?O contacts exist, as well as five C—H?Cl close contacts. The AuCl4]? anion was found to be distorted square planar.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号