Abstract: | The title salt, methyl (1R,2R,3S,5S,8S)‐3‐benzoyloxy‐8‐methyl‐8‐azabicyclo3.2.1]octane‐2‐carboxylate tetrachloroaurate(III), (C17H22NO4)AuCl4], has its protonated N atom intramolecularly hydrogen bonded to the O atom of the methoxycarbonyl group N?O = 2.755 (6) Å and N—H?O = 136°]. Two close intermolecular C—H?O contacts exist, as well as five C—H?Cl close contacts. The AuCl4]? anion was found to be distorted square planar. |