Abstract: | The molecule of the title compound, Hg(C13H9N2O2S)2], has approximate twofold rotation symmetry, with the Hg atom in an essentially linear two‐coordinate HgS2 environment supported by secondary π interactions with the nitrophenyl rings of both ligands. The ligands are in the imine–thiolate rather than the amine–thione tautomeric form. |