catena‐Poly[[copper(II)‐μ‐2‐[bis(2‐pyridylmethyl)amino]butyrato‐κ4N,N′,N′′,O:κO′] perchlorate] |
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Authors: | Seung‐Chul Choi Jaejung Ko Sang Ook Kang Won‐Sik Han Ki‐Young Choi |
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Abstract: | The copper(II) ion in the syn–anti carboxylate‐bridged one‐dimensional zigzag chain title complex, {[Cu(C16H18N3O2)]ClO4}n, exhibits a distorted trigonal–bipyramidal environment. Two N atoms and one carboxylate O atom of the ligand form the basal plane, while the axial positions are filled by an N atom of the ligand and one O atom belonging to the carboxylate group of an adjacent molecule. The crystal packing is enhanced by C—H⋯O(perchlorate) hydrogen bonds. |
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