catena‐Poly[bis(ethane‐1,2‐diammonium) [manganese(II)‐di‐μ‐phosphato‐κ4O:O′]]: a one‐dimensional manganese phosphate |
| |
| Authors: | Fabrice O M Gaslain Ann M Chippindale |
| |
| Abstract: | The title compound, {(C2H10N2)2Mn(PO4)2]}n, contains anionic square‐twisted chains of formula Mn(PO4)2]4− constructed from corner‐sharing four‐membered rings of alternating MnO4 and PO4 units. The Mn and P atoms have distorted tetrahedral coordination and the Mn atom lies on a twofold axis. The linear manganese–phosphate chains are held together by hydrogen‐bonding interactions involving the framework O atoms and the H atoms of the ethane‐1,2‐diammonium cations, which lie in the interchain spaces. |
| |
| Keywords: | |
|
|
