Abstract: | The title compound (H2DTMSPEBP]), C14H36O6P2Si2, was crystallized by the slow evaporation of a solution in a 20:1 mixture of pentane and acetone. The H2DTMSPEBP] molecule lies about an inversion center. In the solid state, the molecule exists in an anti configuration, with the molecular backbone C—C bond located on an inversion center. The compound exists in the solid state as hydrogen‐bonded infinite sheets in the ab plane, unlike the methylene analogue, which exists as hydrogen‐bonded infinite chains, demonstrating an `even–odd' effect of the length of the backbone alkyl chain. |