Abstract: | The crystal structures of the two organic–inorganic hybrids bis(4‐aminopyridinium) hexachloridostannate(IV), (C5H7N2)2SnCl6], and bis(p‐toluidinium) hexachloridostannate(IV), (C7H10N)2SnCl6], differ in the way their cations pack in the layered structures. The Sn atom in the 4‐aminopyridinium compound lies on an inversion centre. |