Metallophilic interactions in iodido(2,2′:6′,2′′‐terpyridine)platinum(II) diiodidoaurate(I) |
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| Authors: | Christina S. Angle Kathryn J. Woolard Michael I. Kahn James A. Golen Arnold L. Rheingold Linda H. Doerrer |
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| Abstract: | In the title compound, [PtI(C15H11N3)][AuI2], the [PtI(terpy)]+ cations (terpy is 2,2′:6′,2′′‐terpyridine) stack in pairs about inversion centers through Pt...Pt interactions of 3.5279 (5) Å. The [AuI2]− anions also exhibit pairwise stacking, with Au...I distances of 3.7713 (5) Å. The [PtI(terpy)]+ cations and [AuI2]− anions aggregate forming infinite arrays of stacked ...({[PtI(terpy)]+...[PtI(terpy)]+}...{[AuI2]−...[AuI2]−})... units. |
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