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2,5‐Dimethyl‐6,7‐dihydrobenzo[h]pyrazolo[1,5‐a]quinazoline and 2‐tert‐butyl‐5‐methyl‐6,7‐dihydrobenzo[h]pyrazolo[1,5‐a]quinazoline
Authors:Jaime Portilla  Jairo Quiroga  Justo Cobo  John N Low  Christopher Glidewell
Abstract:In both 2,5‐dimethyl‐6,7‐dihydrobenzoh]pyrazolo1,5‐a]quinazoline, C16H15N3, (I), and 2‐tert‐butyl‐5‐methyl‐6,7‐dihydrobenzoh]pyrazolo1,5‐a]quinazoline, C19H21N3, (II), which crystallizes with Z′ = 2 in the space group P, the non‐aromatic carbocyclic rings adopt screw‐boat conformations. The molecules of (I) are linked into chains of rings by a combination of C—H...N and C—H...π(arene) hydrogen bonds, while in (II) there are no hydrogen bonds of any kind.
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