(2,2′‐Bipyridine)bis(tri‐tert‐butoxysilanethiolato‐κS)lead(II) and (4,7‐diphenyl‐1,10‐phenanthroline‐κ2N,N′)bis(tri‐tert‐butoxysilanethiolato‐κS)lead(II) benzene hemisolvate |
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| Authors: | Jaroslaw Chojnacki Magdalena Kloskowska Urszula Wjtowicz Wieslaw Wojnowski |
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| Abstract: | In the title mononuclear lead silanethiolates, Pb(C12H27O3SSi)2(C10H8N2)], (I), and Pb(C12H27O3SSi)2(C24H16N2)]·0.5C6H6, (II), the Pb atom shows a distorted square‐pyramidal coordination with a PbON2S2 core in which one S atom lies in an axial position. Intermolecular π–π and C—H...π interactions stabilize the structures. The benzene solvent molecule in (II) lies on an inversion centre. |
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