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Poly[[[aqua­(2,2′‐bipyridine‐κ2N,N′)manganese(II)]‐μ3‐acetyl­enedicarboxylato‐κ3O:O′:O′′] monohydrate]
Authors:Huan‐Yu Wang  Li‐Hua Huo  Shan Gao  Jing‐Gui Zhao
Abstract:In the title complex, {Mn(C4O4)(C10H8N2)(H2O)]·H2O}n, each MnII ion has a distorted octa­hedral coordination formed by two N atoms of a 2,2′‐bipyridine ligand, three carboxyl O atoms of three different acetyl­ene­dicarboxyl­ate ligands and one coordinated water mol­ecule. The acetyl­ene­dicarboxyl­ate ligands act in a tridentate mode connecting adjacent MnII ions and constructing a two‐dimensional structure which can be regarded as an unusual plywood‐like stacked network.
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