Poly[[[aqua(2,2′‐bipyridine‐κ2N,N′)manganese(II)]‐μ3‐acetylenedicarboxylato‐κ3O:O′:O′′] monohydrate] |
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Authors: | Huan‐Yu Wang Li‐Hua Huo Shan Gao Jing‐Gui Zhao |
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Abstract: | In the title complex, {Mn(C4O4)(C10H8N2)(H2O)]·H2O}n, each MnII ion has a distorted octahedral coordination formed by two N atoms of a 2,2′‐bipyridine ligand, three carboxyl O atoms of three different acetylenedicarboxylate ligands and one coordinated water molecule. The acetylenedicarboxylate ligands act in a tridentate mode connecting adjacent MnII ions and constructing a two‐dimensional structure which can be regarded as an unusual plywood‐like stacked network. |
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