Abstract: | Mg2Ru2Cl10O·16H2O {dimagnesium μ‐oxo‐bispentachlororuthenate(IV)] hexadecahydrate} crystallizes in the monoclinic system (space group P21/c). The structure consists of layers of Ru2Cl10O]4? anions, Mg(H2O)6]2+ cations and water molecules stacked along the a axis. Only the O atom bonded to Ru occupies the 2a site with symmetry. All the other atoms occupy general 4e sites. The crystal structure is stabilized by O—H?O and O—H?Cl interactions. |