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Al2O3自电解质溶液中吸附CrO4^2^-的特性研究
引用本文:木冠南,侯秀英. Al2O3自电解质溶液中吸附CrO4^2^-的特性研究[J]. 化学学报, 1988, 46(2): 172-175
作者姓名:木冠南  侯秀英
作者单位:云南大学化学系
摘    要:本文特别延长了pH范围(2-10),详细研究pH、温度、外加正负离子对CrO4^2^-吸附量的影响,说明这种吸附主要是以离子交换方式进行的,并认为表面活性点是产生这类吸附的重要原因.

关 键 词:氧化铝  吸附  离子交换  铬酸盐P  电解质  表面活性  阴离子  

Characteristic study of adsorption of chromate anion from electrolytic solution on alumina
MU GUANNAN,HOU XIUYING. Characteristic study of adsorption of chromate anion from electrolytic solution on alumina[J]. Acta Chimica Sinica, 1988, 46(2): 172-175
Authors:MU GUANNAN  HOU XIUYING
Abstract:The adsorption isotherms of chromate (CrO42-) from electrolytic solution (0.01M NaCl) on Al2O3 were determine at various pH (2-10) and concns. Max. adsorption occurs at pH u4.5. Adsorption of chromate decreases to 0 near the PZC (pH 9). The presence of some anions tends to decrease chromate adsorption. The order is citrate > PO43- > SO42- > NO3-. The presence of some cation tends to increase chromate adsorption. The order is Ba2+ > Ni2+ > K+. Chromate adsorption is not influenced by temperature These results are explained and the adsorption mechanism is discussed.
Keywords:ALUMINIUM OXIDE  ADSORPTION  ION EXCHANGING  CHROMATE P  ELECTROLYTE  SURFACE ACTIVITY  ANION
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