LaBiTe3: An unusual thermoelectric material

Using first‐principles calculations and semi‐classical Boltzmann transport theory, the thermoelectric properties of LaBiTe₃ are studied. The band gap and, hence, the thermoelectric response are found to be easily tailored by application of strain. Independent of the temperature, the figure of merit turns out to be maximal at a doping of about 1.6 × 10²¹ cm^–3. At room temperature we obtain values of 0.4 and 0.5 for unstrained and moderately strained LaBiTe₃, which increases to 1.1 and 1.3 at 800 K. A large spin splitting is observed in the conduction band at the T point. Therefore, LaBiTe₃ merges characteristics that are interesting for thermoelectric as well as spintronic devices. (© 2014 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)