Palladium-catalyzed isomerization of 1-hexene |
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| Authors: | Gomboo Myagmarsuren Vitalii S Tkach and Fedor K Shmidt |
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| Institution: | (1) National University of Mongolia Ulaanbaatar, 210646, Mongolia;(2) Irkutsk State University, Irkutsk, 664003, Russia |
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| Abstract: | The isomerization of 1-hexene over Pd(acac)2 + BF3OEt2 and Pd(acac)2 + PPh3 + BF3OEt2 catalyst systems proceeds by the consecutive-parallel scheme. Tetracoordinate square-planar Pd hydrides bearing two vacant
coordination sites are likely to be catalytically active species for the isomerization of hexene-1.
This revised version was published online in June 2006 with corrections to the Cover Date. |
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| Keywords: | isomerization palladium 1-Hexene |
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