Enantiospecific,stereospecific total synthesis of the oxindole alkaloid alstonisine |
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| Authors: | Wearing Xiangyu Z Cook James M |
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| Affiliation: | Department of Chemistry, University of Wisconsin-Milwaukee, Milwaukee, Wisconsin 53201, USA. |
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| Abstract: | [reaction: see text] The total synthesis of alstonisine was accomplished in enantiospecific fashion in an overall yield of 12% (from tryptophan methyl ester) in 17 reaction vessels. The structure of alstonisine (1) has been determined by NOE spectroscopic experiments and was confirmed by single-crystal X-ray analysis. |
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