Free radical-mediated vinyl amination: access to N,N-dialkyl enamines and their beta-stannyl and beta-thio derivatives |
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| Authors: | Prabhakaran Erode N Nugent Benjamin M Williams Amie L Nailor Kristen E Johnston Jeffrey N |
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| Institution: | Department of Chemistry, Indiana University, Bloomington, Indiana 47405-7102, USA. |
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| Abstract: | reaction: see text] The first examples of free radical-mediated vinyl amination are described by nonconventional vinyl radical addition to azomethine nitrogen. This new vinyl amination protocol is mild and provides convenient synthetic access to nonstabilized N,N-dialkyl enamines and tandem bond-forming processes. |
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