| t—BuNO二聚体在不同溶剂中裂解机理的研究 |
| |
| 引用本文： | 马先勇 唐洁. t—BuNO二聚体在不同溶剂中裂解机理的研究[J]. 光谱学与光谱分析, 1997, 17(5): 124-127 |
| |
| 作者姓名： | 马先勇 唐洁 |
| |
| 作者单位： | [1]湖南医科大学肿瘤研究肿瘤分子生物学研究室 [2]湖南医科大学生物化学教研室 |
| |
| 摘 要： | 本文利用＾１ＨＮＭＲ，ＵＶ－Ｖｉｓ方法，研究了ｔ－ＢｕＮＯ二聚体在有机溶剂及水溶液中的裂解反应产物，分析了其反应的动力学，提出了在非极性的有机相中ｔ－ＢｕＮＯ二聚体为均裂反应，而在极性的水相中为均裂和异裂同时进行的竞争反应。
|
| 关 键 词： | 裂解反应 亚硝基正丁烷 二聚体 自旋捕获剂 |
STUDY ON CLEAVAGE MECHANISMS OF DIMER (t Bu) 2NO IN SEVERAL SOLVENT PHASES |
| |
| X Ma,J Tang. STUDY ON CLEAVAGE MECHANISMS OF DIMER (t Bu) 2NO IN SEVERAL SOLVENT PHASES[J]. Spectroscopy and Spectral Analysis, 1997, 17(5): 124-127 |
| |
| Authors: | X Ma J Tang |
| |
| Affiliation: | Cancer Research Institute, Hunan Medical University, Changsha. |
| |
| Abstract: | In this paper,we studied the cleavage products of dimer t BuNO in aqueous and organic solutions using method of 1HNMR and UV Vis,analyzed the reactive kinetics,put forward that dimer (t Bu) 2NO homolytically cleavaged in nonpolar organic solution,and that dimer (t Bu) 2NO homolytically and heterolyticall cleavaged in a competitive manner in polar aqueous solution. |
| |
| Keywords: | Dimer (t Bu) 2NO Cleavage reaction Competitive reaction |
| 本文献已被 CNKI 维普 等数据库收录！ |
