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Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane |
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| Authors: | Huertos Miguel A Weller Andrew S |
| Institution: | Department of Chemistry, Inorganic Chemistry Laboratories, University of Oxford, Oxford, OX1 3QR, UK. |
| Abstract: | Active species, product distributions and a suggested catalytic cycle are reported for the dehydrocoupling of the phosphine-borane H(3)B·P(t)Bu(2)H to give HP(t)Bu(2)BH(2)P(t)Bu(2)BH(3) using the Rh(COD)(2)]BAr(F)(4)] pre-catalyst. |
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