Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. XXIV. Darstellung und Eigenschaften von Tetrabenzylmolybdän und -uran |
| |
Authors: | K.-H. Thiele,R. Opitz,E. K hler |
| |
Affiliation: | K.-H. Thiele,R. Opitz,E. Köhler |
| |
Abstract: | Contributions to the Chemistry of Transition Metal Alkyl Compounds. XXIV. Preparation and Properties of Tetrabenzyl Molybdenum and Tetrabenzyl Uranium Tetrabenzyl molybdenum, (C6H5CH2)4Mo, can be obtained by the reaction of MoCl4 · 2 THF with dibenzyl magnesium. The compound forms darkbrown crystals, which are stable at room temperature. The analogous reaction of UCl4 · 3 THF with dibenzyl magnesium yields a reddish brown complex of tetrabenzyl uranium of the formula (C6H5CH2)4U · MgCl2. The synthesized compounds are characterized more in detail. |
| |
Keywords: | |
|
|