Gas generation and preconcentration coupled to gas phase molecular absorption spectrometry: a powerful tool for the simultaneous determination of analytes forming volatile compounds |
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Authors: | J. Galban Susana Cabredo Felix Gallarta Isabel Sanz Margarita Perez Jesus Sanz |
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Affiliation: | (1) Department of Chemistry (Analytical Chemistry), University of La Rioja, E-26001 Logroño, Spain;(2) Department of Analytical Chemistry, Faculty of Sciences, University of Zaragoza, E-50009 Zaragoza, Spain |
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Abstract: | Different methods for a simultaneous determination of several analytes forming volatile compounds at room temperature are described. The main steps of these methods are: continuous generation, collection in a cryogenic trap, revolatilization, measurement of the volatile compounds by Gas Phase Molecular Absorption Spectrometry and resolution by multi-wavelength methods. Several mixtures containing 2, 3 or 4 components have been studied: 1) elements forming covalent hydrides; 2) arsenic organometallic compounds forming volatile gases with a similar structure to arsine; and 3) sulphur species that can evolve volatile compounds. Under the optimum conditions obtained for each mixture, detection limits range from 0.8 ng/mL (dimethylarsinic acid) to 2 g/mL (SCN-). |
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